A thermistor is a type of resistor used to measure temperature changes, relying on the change in its resistance with changing temperature. Thermistor is a portmanteau of the words thermal and resistor.

If we assume that the relationship between resistance and temperature is linear (i.e. we make a first-order approximation), then we can say that:

$\backslash Delta\; R=k\backslash Delta\; T$

where

$\backslash Delta\; R$ = change in resistance

$\backslash Delta\; T$ = change in temperature

$k$ = first-order temperature coefficient of resistance

Thermistors can be classified into two types depending on the sign of $k$. If $k$ is positive, the resistance increases with increasing temperature, and the device is called a positive temperature coefficient (PTC) thermistor, posistor. If $k$ is negative, the resistance decreases with increasing temperature, and the device is called a negative temperature coefficient (NTC) thermistor. Resistors that are not thermistors are designed to have the smallest possible $k$, so that their resistance remains almost constant over a wide temperature range.

Steinhart Hart equation

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In practice, the linear approximation (above) works only over a small temperature range. For accurate temperature measurements, the resistance/temperature curve of the device must be described in more detail. The Steinhart-Hart equation is a widely used third-order approximation:

$T=\{1\backslash over\{a+b\backslash ln\{R\}+c\backslash left(\backslash ln\; R\; \backslash right)^3\}\}$

where a, b and c are called the Steinhart-Hart parameters, and must be specified for each device. T is the temperature in kelvins and R is the resistance in ohms. To give resistance as a function of temperature, the above can be rearranged into:

$R=e^$

where

$\backslash alpha=\backslash over\; c\}$ and $\backslash beta=\backslash sqrt\backslash right)\}^3\}+\}$

The error in the Steinhart-Hart equation is generally less than 0.02 °C in the measurement of temperature. As an example, typical values for a thermistor with a resistance of 3000 ohms at room temperature (25 °C = 298.15 K) are:

$a\; =\; 1.40\; \backslash times\; 10^\{-3\}$

$b\; =\; 2.37\; \backslash times\; 10^\{-4\}$

$c\; =\; 9.90\; \backslash times\; 10^\{-8\}$

B parameter equation

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NTC thermistors can also be characterised with the B parameter equation:

$1/T=1/T\_0\; +\; B\backslash cdot\; \backslash ln\; \{R/R\_0\}$    ( + c ln³ R +...)

or

$R=R\_0\backslash cdot\; e^\{B\backslash cdot\; (1/T-1/T\_0)\}$

or

$R=r\_\backslash infty\backslash cdot\; e^\{B/T\}$

or

$T=\{B\backslash over\; \{\; \{\backslash ln\{R\; /\; r\_\backslash infty\}\}\}\}$

where

R₀ is the resistance at temperature T₀ (usually 25°C)

$r\_\backslash infty=R\_0\; \backslash cdot\; e^\{-\{B/T\_0\}\}$

$B=-b\backslash cdot\; \backslash ln\{R\_0\}$

Conduction model

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Many NTC thermistors are made from a pressed disc or cast chip of semiconducting material such as a sintered metal oxide. They work because raising the temperature of a semiconductor increases the number of electrons able to move about and carry charge - it promotes them into the conducting band. The more charge carriers that are available, the more current a material can conduct. This is described in the formula:

$$

I = n \cdot A \cdot v \cdot e

$I$ = electric current (ampere)
$n$ = density of charge carriers (count/m³)
$A$ = cross-sectional area of the material (m²)
$v$ = velocity of charge carriers (m/s)
$e$ = charge of an electron ($e=1.602\; \backslash times\; 10^\{-19\}$ coulomb)

The current is measured using an ammeter. Over large changes in temperature, calibration is necessary. Over small changes in temperature, if the right semiconductor is used, the resistance of the material is linearly proportional to the temperature. There are many different semiconducting thermistors and their range goes from about 0.01 kelvin to 2000 kelvins (-273.14 °C to 1700 °C).

Most PTC thermistors are of the "switching" type, which means that their resistance rises suddenly at a certain critical temperature. The devices are made of a doped polycrystalline ceramic containing barium titanate (BaTiO₃) and other compounds. The dielectric constant of this ferroelectric material varies with temperature. Below the Curie point temperature, the high dielectric constant prevents the formation of potential barriers between the crystal grains, leading to a low resistance. In this region the device has a small negative temperature coefficient. At the Curie point temperature, the dielectric constant drops sufficiently to allow the formation of potential barriers at the grain boundaries, and the resistance increases sharply. At even higher temperatures, the material reverts to NTC behaviour. The equations used for modeling this behaviour were derived by W. Heywang and G. H. Jonker in the 1960s.

Another type of PTC thermistor is the polymer PTC, which is sold under brand names such as "Polyfuse", "Polyswitch" and "Multiswitch". This consists of a slice of plastic with carbon grains embedded in it. When the plastic is cool, the carbon grains are all in contact with each other, forming a conductive path through the device. When the plastic heats up, it expands, forcing the carbon grains apart, and causing the resistance of the device to rise rapidly. Like the BaTiO₃ thermistor, this device has a highly nonlinear resistance/temperature response and is used for switching, not for proportional temperature measurement.

Self-heating effects

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When a current flows through a thermistor, it will generate heat which will raise the temperature of the thermistor above that of its environment. If the thermistor is being used to measure the temperature of the environment, this self-heating effect will introduce an error if a correction is not made.

The electrical power input to the thermistor is just

$P\_E=IV\backslash ,$

where I is current and V is the voltage drop across the thermistor. This power is converted to heat, and this heat energy is transferred to the surrounding environment. The rate of transfer is well described by Newton's law of cooling:

$P\_T=K(T(R)-T\_0)\backslash ,$

where T(R) is the temperature of the thermistor as a function of its resistance R, $T\_0$ is the temperature of the surroundings, and K is the dissipation constant, usually expressed in units of milliwatts per degree C. At equilibrium, the two rates must be equal.

$P\_E=P\_T\backslash ,$

The current and voltage across the thermistor will depend on the particular circuit configuration. As a simple example, if the voltage across the thermistor is held fixed, then by Ohm's Law we have $I=V/R$ and the equilibrium equation can be solved for the ambient temperature as a function of the measured resistance of the thermistor:

$T\_0=T(R)\; -\backslash frac\{V^2\}\{KR\}\backslash ,$

The dissipation constant is a measure of the thermal connection of the thermistor to its surroundings. It is generally given for the thermistor in still air, and in well stirred oil. Typical values for a small glass bead thermistor are 1.5 mw/°C in still air and 6.0 mw/°C in stirred oil. If the temperature of the environment is known beforehand, then a thermistor may be used to measure the value of the dissipation constant. For example, the thermistor may be used as a flow rate sensor, since the dissipation constant increases with the rate of flow of a fluid past the thermistor.

Applications

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• PTC thermistors can be used as current-limiting devices for circuit protection, as replacements for fuses. Current through the device causes a small amount of resistive heating. If the current is large enough to generate more heat than the device can lose to its surroundings, the device heats up, causing its resistance to increase, and therefore causing even more heating. This creates a self-reinforcing effect that drives the resistance upwards, reducing the current and voltage available to the device.
• NTC thermistors can be used as inrush-current limiting devices in power supply circuits. They present a higher resistance initially which prevents large currents from flowing at turn-on, and then heat up and become much lower resistance to allow higher current flow during normal operation. These thermistors are usually much larger than measuring type thermistors, and are purpose designed for this application.
• Thermistors are also commonly used in modern digital thermostats and to monitor the temperature of battery packs while charging.

See also

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• Ohm's Law
• Resistor
• Thermocouple
• Thermostat
• Resistance temperature detector

External links

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• The thermistor at bucknell.edu

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