article

Properties

General

Name Silver chloride
Chemical formula AgCl
Appearance White solid

Physical

Formula weight 143.3 amu
Melting point 728 K (455 °C)
Boiling point 1823 K (1550 °C)
Density 5.56 ×103 kg/m3
Crystal structure cubic
Solubility 52 x 10-6g/100g water at 50°C

Thermochemistry

ΔfH0gas ? kJ/mol
ΔfH0liquid ? kJ/mol
ΔfH0solid -127.01 kJ/mol
S0gas, 1 bar ? J/mol·K
S0liquid, 1 bar ? J/mol·K
S0solid 96.25 J/mol·K
Silver chloride (also called silver(I) chloride) is a chemical compound with chemical formula AgCl and is composed of one silver and one chlorine atom. Silver chloride is a white crystalline solid, one of the few metal chlorides insoluble in water. It is soluble, however, in solutions containing the halide ions, thiosulfate ions, or aqueous ammonia, reacting to form complexes according to the following reactions:

AgCl(s) + Cl-(aq) → AgCl2-(aq)

AgCl(s) + 2S2O32-(aq) → Ag*3-(aq) + Cl-(aq)

AgCl(s) + 2NH3(aq) →Ag*+(aq) + Cl-

Silver chloride is used to make photographic film since it turns darker when exposed to light.

To detect the presence of chloride in water, silver nitrate is added and silver chloride crystals will form if chloride is present.

Ag+(aq) + Cl-(aq) → AgCl(s)

Applications


External links


Chlorides | Silver compounds | Metal halides | Coordination compounds

Silberchlorid | Chlorure d'argent | Cloruro d'argento | Zilverchloride | Silverklorid | 氯化银

 

This article is licensed under the GNU Free Documentation License. It uses material from the "Silver chloride".

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