article

Carbonate of potash redirects here. For one of potassium carbonate's impure forms, see potash.

Potassium carbonate
General
Other names Potash, pearlash
Molecular formula K2CO3
Molar mass 138.2 g/mol
Appearance white solid,
deliquescent
CAS number *
Properties
Density and phase 2.29 g/cm3, solid
Solubility in water 112 g/100 ml (20 °C)
Melting point 891 °C
Boiling point decomposes
Basicity (pKb) ?
Structure
Coordination
geometry
?
Crystal structure ?
Thermodynamic data
Std enthalpy change
of formation
, ΔfHosolid
−1151 kJ/mol
Std molar entropy, Sosolid 156 J·K−1·mol−1
Hazards
MSDS External MSDS
EU classification not listed
NFPA 704
Flash point non flammable
RTECS number TS7750000
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Other anions Potassium bicarbonate
Other cations Lithium carbonate
Sodium carbonate
Except where noted otherwise, data are given for
materials in their standard state (at 25 °C, 100 kPa)
Chemical infobox

Potassium carbonate is a white salt, soluble in water (insoluble in alcohol), which forms a strongly alkaline solution. It can be made as the product of potassium hydroxide's absorbant reaction with carbon dioxide. It is a deliquescent (usually damp or wet) solid, used in the production of soap and glass.

Potassium carbonate was first identified in 1742 by Antonio Campanella and is the primary component of potash and the more refined pearlash or salts of tartar. Historically pearlash was created by baking potash in a kiln to remove impurities. The fine white powder remaining was the pearlash. Pearlash has been used for soap, glass, and china production. The first patent issued by the U.S. Patent Office was awarded to Samuel Hopkins in 1790 for an improved method of making pearlash.

In late 18th century North America, before the development of baking powder, pearlash began to be used as a leavening agent in "quick breads".

Today potassium carbonate is prepared commercially by the electrolysis of potassium chloride. The resulting potassium hydroxide is then carbonated using carbon dioxide to form potassium carbonate, which is often used to produce other potassium compounds.

Other terms for potassium carbonate include:

  • Carbonate of potash
  • Dipotassium carbonate
  • Dipotassium salt
  • Pearl ash
  • Potash
  • Salt of tartar
  • Salt of wormwood
  • Cream of tartar

Structure


References


A Dictionary of Science, Oxford University Press Inc., New York 2003

External links


Carbonates | Leavening agents | Potassium compounds | Deliquescent substances

Kaliumcarbonat | Carbonato de potasio | Kaliumcarbonaat | 炭酸カリウム | Węglan potasu | Калијум карбонат | Карбонат калію | 碳酸鉀

 

This article is licensed under the GNU Free Documentation License. It uses material from the "Potassium carbonate".

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