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Potassium bicarbonate
General
Systematic name ?
Other names ?
Molecular formula KHCO3
SMILES ?
Molar mass ?.?? g/mol
Appearance ?
CAS number *
Properties
Density and phase ? g/cm3, ?
Solubility in water ? g/100 ml (?°C)
Melting point ?°C (? K)
Boiling point ?°C (? K)
Acidity (pKa) ?
Basicity (pKb) ?
Chiral rotation *D
Viscosity ? cP at ?°C
Structure
Molecular shape ?
Coordination
geometry
?
Crystal structure ?
Dipole moment ? D
Hazards
MSDS External MSDS
Main hazards ?
NFPA 704
Flash point ?°C
R/S statement R: ?
S: ?
RTECS number ?
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Other anions ?
Other cations ?
Related ? ?
Related compounds ?
Except where noted otherwise, data are given for
materials in their standard state (at 25°C, 100 kPa)
Chemical infobox

Potassium bicarbonate (also known as potassium hydrogen carbonate or potassium acid carbonate), is a colorless, odorless, slightly basic, salty substance. The compound is used as a source of carbon dioxide for leavening in baking, extinguishing fire in powder fire extinguishers, acting as a reagent, and a strong buffer in medications. The US Food and Drug Administration (FDA) recognizes potassium bicarbonate as "generally recognized as safe". It is used as a base in foods to regulate pH.

Potassium bicarbonate is soluble in water, and is often found added to bottled water to affect taste; however it is not soluble in alcohol. Decomposition of the substance occurs between 100°C and 120°C into K2CO3 (potassium carbonate), H2O (water), and CO2 (carbon dioxide). In concentrations greater than 0.5%, KHCO3 can have phytotoxic effects on plants (potassium bicarbonate has widespread use in crops, especially for neutralizing acidic soil), although there is no evidence of human carcinogenicity, no adverse effects of overexposure, and no LD50.

Physically, potassium bicarbonate occurs as a crystal or a soft white granular powder. It has a CAS No *. It is manufactured by reacting potassium carbonate with carbon dioxide and water via electrolysis:

K2CO3 + CO2 + H2O -> 2 KHCO3

Potassium bicarbonate is used as a fire suppression agent ("BC powder") in some dry powder fire extinguishers, as the principial component of the Purple-K powder. It is the only dry chemical fire suppression agent recognized by the National Fire Protection Association for firefighting at airport crash rescue sites. It is about twice as effective in fire suppression than sodium bicarbonate. *

External links


Potassium compounds | Bicarbonates | Fire suppression agents

炭酸水素カリウム

 

This article is licensed under the GNU Free Documentation License. It uses material from the "Potassium bicarbonate".

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