In the arts of painting, web design, and photography, color theory is a set of basic rules for mixing color to achieve a desired result. As pigment and light are different in terms of how they combine to create colors, so too are the rules for dealing with each. White light is composed of the mixture of the three primary hues red, green and blue. Black is approximated in pigment by mixing the primaries cyan, magenta and yellow (the imperfect primaries blue, red and yellow are the more traditional primaries due to their colorfast properties and physical pigment availability.)
On his Theory of Colors, Goethe proposed a symmetric color circle, which comprises both the Newtonian and complementary spectra. In contrast, Newton's color circle, with seven colors subtending unequal angles, did not exhibit the symmetry and complementarity that Goethe regarded as essential characteristics of color. For Newton, only spectral colors could count as fundamental. Goethe's more empirical approach led him to recognize the essential role of (nonspectral) magenta in a complete color circle.
Mixing colors of light, usually Red/Green/Blue, is done using the additive color system (also referred to as the "RGB Model" or "RGB color space"). The basis for these colors are the color-sensitive cone cells in the human retina. All the possible colors that can be created by mixing these three colored lights are referred to as the gamut of those particular lights. All these colors when mixed together in equal portions create white; when no color of light is present, one perceives black. Additive color applies to computer monitors, television, and video projectors, all of which use combinations of red, green, and blue phosphors.
For printing purposes and in painting, the colors used are cyan, magenta, and yellow; this model is called the "CMY model". In the CMY model, black is created by mixing all colors, and white is the absence of any colors (assuming a white medium). As colors are subtracted to produce white, this is also called the subtractive color model. A mix of Cyan, Magenta, and Yellow actually gives a muddy black so normally true black ink is used as well; when black is added, this color model is called the "CMYK model", where the K stands for "key". The CMY color model is also more accurate for pigment-mixing.
Also commonly used in painting is the RYB color model, in which red, yellow, and blue are the primary colors. It is possible to mix red, yellow (not green) and blue paint to get orange, purple and a non-primary shade of green paint, due to subtractive mixing. This model is largely used for traditional reasons; red and blue are in fact approximations for magenta and cyan respectively - the CMY color model can more easily display a full gamut of colors than can RYB.
A much more detailed discussion of color models, particularly as they apply to color for computer displays, can be found in the color space article.
Only fictional "primary" colors can mix all possible colors. These primaries are arbitrary concepts, used in mathematical models of color vision. They do not represent real color sensations, or even real nerve impulses or brain processes. In other words, all perfect "primary" colors are completely imaginary. For more details, see the color vision article.
On the other hand, any three (or four or five or six) real "primary" colors cannot mix all the colors in any medium, and this is always true no matter which "primary" colors are chosen and no matter which medium — inks, paints, dyes, filters, phosphors, artificial lights, or monospectral lights — is used to mix the colors. In other words, all mixable "primary" colors are incomplete or imperfect.
Newton was the first to devise a color wheel (Newton's circle of colors); his differed from the modern one in going directly from violet to red: modern ones have purple between them. Newton only included spectral colors in his circle of colors; as a result, purple was ommitted.
Neutrals may be created by mixing grey with pure colors or by mixing two complementary colors (opposite colors). The color made by mixing complements may be further neutralized by mixing grey.
Traditional color theory using the RYB color wheel states that the primary colors (red, blue, yellow) combine to form the three secondary colors (purple, green, orange). A primary color will have a secondary color as its opposite — ergo red's complement is green, blue's is orange, and yellow's is purple. Adding a complementary color to a color on the canvas is the traditional technique for making shadows, as well as for choosing a balance of color overall, so that the eye does not tire from an overuse of red, for example.
Unfortunately, when used in practice, combining primary colors using the RYB color wheel often results in secondary colors that lack vibrancy or are "muddy" — appear as if they are "dirty" and turning brown. Mixing complementary colors does result in a darker color, but the resulting color may appear dull and muddy as well.
Mixing pigments using the CMY color wheel greatly reduces this problem. Combining CMY primary colors (cyan, magenta, and yellow) forms the three CMY secondary colors (blue, red, and green) in a more vibrant, purer form than the RYB color wheel. Complements around the wheel — cyan opposite red, magenta opposite green, and yellow opposite blue — are more properly matched, and when combined result in neutral dark grays and blacks instead of dark browns or muddy blacks.
Although in theory, one should be able to mix all colors using the CMY color wheel using just the pure pigments of cyan, magenta, and yellow, the mixed colors usually are still duller than their pure primary counterparts. This is especially apparent between cyan/magenta, and yellow/cyan. In order to obtain a more vibrant version of a mixed secondary color, one would replace the dull mixed hue with a more vibrant natural pigment secondary color of the same hue. For instance, mixing primaries hanza yellow and phthalocyanine cyan — effectively yellow and cyan — will result in a dull blue-green secondary color. In order to achieve a more vibrant blue-green, the natural pigment phthalocyanine green would be used. By replacing mixed secondary colors with natural pigment secondary colors, mixed tertiary colors will be more vibrant than mixed from the primaries alone.
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