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Calcium sulfate
General
Other names Plaster of Paris
Gypsum
Drierite®
whiskers crystal
Molecular formula CaSO4
Molar mass 136.142 g/mol
(anhydrous)
Appearance white solid
see also text
CAS number *
(anhydrous)
Properties
Density and phase 22.96 g/cm3, solid
Solubility in water 0.24 g/100 ml (20 °C)
Melting point 1460°C (anhydrous)
Refractive Index 1.57
Mohs hardness 3.5
Structure
Coordination geometry ?
Crystal structure orthorhombic
Thermodynamic data
Standard enthalpy
of formation
Δfsolid
-1434.5 kJ/mol
Standard molar entropy
solid
? J.K–1.mol–1
Heat of fusion 205.668
Specific Heat Capacity 0.732324 J/g-°C (anhydrous)
Safety data
PEL-TWA (OSHA) 15 mg/m3
RTECS number WS6920000
NFPA 704
Supplementary data page
Structure & properties n, εr, etc.
Thermodynamic data Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Other cations Magnesium sulfate
Strontium sulfate
Related drying agents Calcium chloride
Magnesium sulfate
Related compounds Plaster of Paris
Gypsum
Except where noted otherwise, data are given for
materials in their standard state (at 25°C, 100 kPa)
Chemical infobox

Calcium sulfate is a common laboratory and industrial chemical. In its anhydrous form, it is sold as a laboratory desiccant under the name Drierite®. The hemihydrate is better known as plaster of Paris, while the dihydrate occurs naturally as gypsum. Depending on the method of calcination of calcium sulfate dihydrate specific hemihydrates are obtained: alpha-hemihydrate and beta-hemihydrate. Alpha-hemihydrate crystals are more prismatic than beta-hemihydrate crystals and when mixed with water form a much stronger and harder superstructure.

External links


Calcium compounds | Sulfates

סידן גופרתי | Сульфат кальция | แคลเซียมซัลเฟต | Сульфат кальцію

 

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