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Tollens' reagent is usually ammoniacal silver nitrate, but can also be other things, as long as there is an aqueous diamminesilver(I) complex.
Uses
The diaminesilver(I) complex is an oxidizing agent, which is itself reduced to silver metal, which in a clean glass reaction vessel forms a "silver mirror". This feature is used as a test for aldehydes, which are oxidized to carboxylic acids.
Once it has been identified that there is a carbonyl group on the organic molecule using 2,4-dinitrophenylhydrazine (also known as Brady's reagent or 2,4-DNPH), Tollens' reagent can be used to ascertain whether the compound is a ketone or an aldehyde. When adding the aldehyde or ketone to Tollens' reagent, put test tube in a warm water bath.
If the reactant under test is an aldehyde, Tollens' test results in a silver mirror. Otherwise, a yellowish mirror may or may not be formed.
Laboratory Preparation
- To aqueous silver nitrate, add a drop of dilute sodium hydroxide. A brown precipitate of silver oxide will form.
- Add ammonia until the precipitate just dissolves.
- This is ammoniacal silver nitrate, *NO3 (aq).
Safety
The reagent should be freshly prepared and never stored for more than a couple of hours. After the test has been performed, the resulting mixture should be acidified with dilute acid before disposal. These precautions are to prevent the formation of the highly explosive fulminating silver, which is mostly silver nitride, Ag3N.
External links
- Video of experimental process involving Tollens' reagent
- Tollens' reagent on www.wiu.edu Link
"Tollens' reagent"