article

Systematic name
Other names xxx, xxx
Molecular formula XxXxXx
Molar mass xx.xx g/mol
Density x.xxx g/cm3
Solubility (water) x.xx g/l
Melting point xx.x °C
Boiling point xx.x °C
CAS number *
Chemical infobox
Magnesium diboride (MgB2) is an inexpensive and simple superconductor that can be synthesized by high temperature reaction between boron and magnesium. It was announced in the journal Nature in March 2001. Its critical temperature (39 K) is the highest amongst conventional superconductors (phonon-mediated superconductors). This material was first synthesized in 1953 but its superconducting properties were not discovered until half a century later.

Formation beings at 650 Celsius. However, since Magnesium metal melts at 651 Celsius, the reaction mechanism is considered to be moderated by magnesium vapor diffusion across boron grain boundaries. At conventional processing temperatures, sintering is minimal, although enough grain recrystallization occurs to permit Josephson Quantum tunnelling. Bulk samples are extremely porous and show poor ceramic properties, yet its superconducting properties make it useful for a variety of applications. Thin coatings can be used in superconducting Radio Frequency Cavities to minimize energy loss and reduce the inefficiency of liqiuid helium cooled niobium cavities. Due to the low cost of its constituent materials, MgB2, has promise for use in superconducting power lines.

Though a conventional superconductor, it is a rather unusual one. Its electronic structure is such that there exist two types of electrons at the Fermi level with widely differing behaviours, one of them being much more strongly superconducting than the other. This is at odds with usual theories of phonon-mediated superconductivity which assume that all electrons behave in the same manner. For this reason, theoretical understanding of the properties of MgB2 is not yet achieved, particularly so in the presence of magnetic field.

External links


Borides | Magnesium compounds | Superconductors

Magnesiumdiborid | 二ホウ化マグネシウム | Магнезијум диборит | 硼化鎂

 

This article is licensed under the GNU Free Documentation License. It uses material from the "Magnesium diboride".

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