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Fluoroantimonic acid HFSbF5 is a mixture of hydrofluoric acid and antimony pentafluoride, and is the strongest known superacid system. In this system, hydrofluoric acid releases the proton (H+), and the conjugate base (F−) is effectively sequestered by forming a strong coordinate bond with the fluorophilic antimony pentafluoride. The result of this coordinated bond is a large octahedral anion (SbF6−), which is a very weak nucleophile and a very weak base. The proton effectively becomes a "free proton", which accounts for the system's extreme acidity. Fluoroantimonic acid is 2(twenty quintillion) times stronger than 100% sulfuric acid. The autodissociation of fluoroantimonic acid in water and dissociation back to its constituents can be abbreviated as

Comparison with other acids

External links


Inorganic compounds | Superacids

Kwas fluoroantymonowy

 

This article is licensed under the GNU Free Documentation License. It uses material from the "Fluoroantimonic acid".

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