Iron is durable, relatively cheap, non-toxic, easy to cast (mold) and shape, and has excellent heat retention and diffusion. These properties make cast iron a natural choice for cookware. The cast iron used to make cookware is itself made from pig and scrap iron, with a small amount of silicon and graphite.
Because cast iron will react with or stain many foods, bare cast iron cookware must be seasoned. Cast iron cookware is also available with an enamel coating - this cookware doesn't need to be seasoned, but loses some of the other desirable properties of bare cast iron.
Some of the types of cookware made out of bare cast iron include dutch ovens, frying pans, deep fryers, woks, and griddles.
Bare cast iron cookware requires seasoning—impregnation of the cooking surface with oil—to prevent rusting, and to create a non-stick surface. New cast iron must be seasoned before use. Some companies now offer pre-seasoned pans, but, like "home-seasoned" cast iron, these may need to be re-seasoned if they are washed with strong soap or allowed to rust.
The seasoning layer protects the cookware from rusting, provides a non-stick surface for cooking, and protects food from interacting with the iron of the pan. Shortenings typically used for seasoning include lard, hydrogenated cooking oils such as Crisco, and solid palm or coconut oil (in general, oils that are high in saturated fats). Avoid using shortenings that are polyunsaturated - these will get rancid much more quickly. Well-seasoned cast iron cookware will have a very smooth black surface.
Before seasoning, cookware should be thoroughly scrubbed using light dish soap and scouring pads (steel wool is best). If the surface is "natural" (unpolished), it may also be useful to use a wire brush. Scrubbing will remove any dirt or rust, and, in the case of new cookware, will remove the protective coating (wax or machine oil) that new pieces are often shipped with to prevent rust. Rust can also be removed by soaking in a 1:1 solution of vinegar and water.
Once cleaned, cookware can then be seasoned. There are several techniques for seasoning cast iron that vary based on the smoke point of the oil or fat used.
If too much oil or shortening is applied to a pan in the seasoning process, it will pool and gum up when the pan is heated. In this case, the goo can be scraped off and some more grease rubbed over the spot, or the pan can be re-scrubbed and reseasoned. Heating the pan upside-down may help prevent gumming, but will be more likely to drip grease into your oven unless protected by a foiled-lined baking sheet. Seasoning at higher temperatures approaching the smoking point of the oil used will result in darker seasoned coatings in less time that aren't sticky or gummy.
There are several methods for cleaning seasoned bare cast iron cookware:
In all cases, the cookware should be dried thoroughly after washing, and oiled lightly if not already very well seasoned.
For deep cleaning (before re-seasoning), some cast iron collectors also advocate soaking cast iron in a lye solution, or heating the pan in a self-cleaning oven or campfire. Both of these methods have inherent drawbacks, however. Lye can cause serious injury (inluding blindness) if handled improperly, and unevenly heating a cast iron pan may warp or crack the pan.
Some well-known brands of cast iron cookware are:
There are also several brands of cast iron now available that are made in China. These are considered to be of very poor quality by collectors and cooks.
Enameled cast iron is cast iron that has had a vitreous enamel glaze applied to it. This type of cast iron was a popular material for cookware in the late 19th and early to mid-20th centuries, but it has since been largely replaced by more modern metal alloys. It still remains a popular material for making Dutch ovens.
The enamel coating over the cast iron prevents rusting, eliminates the need to season the metal, and allows for more thorough cleaning. Furthermore, pigments used in the enameling process can produce vibrant colors. While enamel coated cast iron doesn't have the seasoning and cleaning issues of bare cast iron, however, it can be several times more costly.
Unlike bare cast iron, enamel coated cast iron typically can't be heated to a high heat, and therefore can't be used for seared or blackened dishes.
Manufacturers still making enameled cast iron cookware include:
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